Cofactor‐Free, Direct Photoactivation of Enoate Reductases for the Asymmetric Reduction of C=C Bonds

Enoate reductases from the family of old yellow enzymes (OYEs) can catalyze stereoselective trans‐hydrogenation of activated C=C bonds. Their application is limited by the necessity for a continuous supply of redox equivalents such as nicotinamide cofactors [NAD(P)H]. Visible light‐driven activation...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Lee, Sahng Ha, Choi, Da Som, Pesic, Milja, Lee, Yang Woo, Paul, Caroline E., Hollmann, Frank, Park, Chan Beum
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5519925/
https://ncbi.nlm.nih.gov/pubmed/28544039
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201702461
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