Structure-Based Insight into the Asymmetric Bioreduction of the C=C Double Bond of α,β-Unsaturated Nitroalkenes by Pentaerythritol Tetranitrate Reductase

Biocatalytic reduction of α- or β-alkyl-β-arylnitroalkenes provides a convenient and efficient method to prepare chiral substituted nitroalkanes. Pentaerythritol tetranitrate reductase (PETN reductase) from Enterobacter cloacae st. PB2 catalyses the reduction of nitroolefins such as 1-nitrocyclohexe...

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Autores principales: Toogood, Helen S., Fryszkowska, Anna, Hare, Victoria, Fisher, Karl, Roujeinikova, Anna, Leys, David, Gardiner, John M., Stephens, Gill M., Scrutton, Nigel S.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2008
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2854801/
https://ncbi.nlm.nih.gov/pubmed/20396603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.200800561
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