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Nonequivalence of Second Sphere “Noncatalytic” Residues in Pentaerythritol Tetranitrate Reductase in Relation to Local Dynamics Linked to H-Transfer in Reactions with NADH and NADPH Coenzymes
[Image: see text] Many enzymes that catalyze hydride transfer reactions work via a mechanism dominated by quantum mechanical tunneling. The involvement of fast vibrational modes of the reactive complex is often inferred in these reactions, as in the case of the NAD(P)H-dependent pentaerythritol tetr...
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| Pubblicato in: | ACS Catal |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical Society
2018
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6516726/ https://ncbi.nlm.nih.gov/pubmed/31119061 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b02810 |
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