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Spectroscopic Definition of the Cu(Z)° Intermediate in Turnover of Nitrous Oxide Reductase and Molecular Insight into the Catalytic Mechanism
Spectroscopic methods and density functional theory (DFT) calculations are used to determine the geometric and electronic structure of Cu(Z)°, an intermediate form of the Cu(4)S active site of nitrous oxide reductase (N(2)OR) that is observed in single turnover of fully reduced N(2)OR with N(2)O. El...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5532879/ https://ncbi.nlm.nih.gov/pubmed/28228011 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13225 |
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