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Determination of the active form of the tetranuclear copper sulfur cluster in nitrous oxide reductase
N(2)OR has been found to have two structural forms of its tetranuclear copper active site, the 4CuS Cu(Z)* form and the 4Cu2S Cu(Z) form. EPR, resonance Raman, and MCD spectroscopies have been used to determine the redox states of these sites under different reductant conditions, showing that the Cu...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3927536/ https://ncbi.nlm.nih.gov/pubmed/24364717 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja411500p |
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