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A Short Synthesis of (±)‐3‐Demethoxyerythratidinone by Ligand‐Controlled Selective Heck Cyclization of Equilibrating Enamines
A short, 5‐step total synthesis of (±)‐3‐demethoxyerythratidinone from a simple pyrrole derivative is described. Features include the formation of gram quantities of a key tricylic aziridine from a challenging photochemical cascade reaction through the use of flow photochemistry. The final step invo...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5488232/ https://ncbi.nlm.nih.gov/pubmed/28470985 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701775 |
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