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Phosphazene-catalyzed desymmetrization of cyclohexadienones by dithiane addition
We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered dithiane nucleophile. Mild reaction conditions allow the formation of diversely functionalized fused bicyclic lactones. The products participate in facially selective additions from the convex surfac...
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| Publicado en: | Beilstein J Org Chem |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Beilstein-Institut
2017
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5433211/ https://ncbi.nlm.nih.gov/pubmed/28546832 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.75 |
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