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Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates

The Rauhut–Currier (RC) reaction represents an efficient method for the construction of carbon–carbon bond in organic synthesis. However, the RC reactions involving allenoate substrates are very rare, and in particular, asymmetric intramolecular RC reaction of allenoates is yet to be discovered. Her...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Yao, Weijun, Dou, Xiaowei, Wen, Shan, Wu, Ji'en, Vittal, Jagadese J., Lu, Yixin
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5059449/
https://ncbi.nlm.nih.gov/pubmed/27698487
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13024
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