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Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates

The Rauhut–Currier (RC) reaction represents an efficient method for the construction of carbon–carbon bond in organic synthesis. However, the RC reactions involving allenoate substrates are very rare, and in particular, asymmetric intramolecular RC reaction of allenoates is yet to be discovered. Her...

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Vydáno v:Nat Commun
Hlavní autoři: Yao, Weijun, Dou, Xiaowei, Wen, Shan, Wu, Ji'en, Vittal, Jagadese J., Lu, Yixin
Médium: Artigo
Jazyk:Inglês
Vydáno: Nature Publishing Group 2016
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5059449/
https://ncbi.nlm.nih.gov/pubmed/27698487
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13024
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