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Rh(i)-catalyzed stereoselective desymmetrization of prochiral cyclohexadienones via highly exo-selective Huisgen-type [3 + 2] cycloaddition

A Rh(i)-catalyzed highly stereoselective desymmetrization of 2-alkynylbenzaldehyde-tethered cyclohexadienones triggered by intramolecular Huisgen-type [3 + 2] cycloaddition has been developed. This method enables convergent construction of complex epoxy-bridged polycyclic ring systems with five cont...

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Bibliografski detalji
Izdano u:Chem Sci
Glavni autori: Gollapelli, Krishna Kumar, Patil, Vaibhav B., Vinaykumar, Allam, Chegondi, Rambabu
Format: Artigo
Jezik:Inglês
Izdano: The Royal Society of Chemistry 2020
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179110/
https://ncbi.nlm.nih.gov/pubmed/34163917
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05543c
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