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Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation
We describe a Rh-catalyzed desymmetrization of all-carbon quaternary centers from α,α-bis(allyl)aldehydes by a cascade featuring isomerization and hydroacylation. This desymmetrization competes with two other novel olefin functionalizations that are triggered by C–H bond activation, including carboa...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4618402/ https://ncbi.nlm.nih.gov/pubmed/26508999 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01553g |
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