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Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
[Image: see text] We report a highly enantioselective CuH-catalyzed Markovnikov hydrosilylation of vinylarenes and vinyl heterocycles. This method has a broad scope and enables both the synthesis of isolable silanes and the conversion of crude products to chiral alcohols. Density functional theory c...
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| Опубликовано в: : | J Am Chem Soc |
|---|---|
| Главные авторы: | , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
American Chemical
Society
2017
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| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5386394/ https://ncbi.nlm.nih.gov/pubmed/28117996 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13029 |
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