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Copper-Catalyzed Regioselective ortho C–H Cyanation of Vinylarenes

A copper-based catalytic technique for the regioselective ortho C–H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives. A copper-catalyzed cyanative dearomatization mechanism is proposed to account for th...

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Detalhes bibliográficos
Main Authors: Yang, Yang, Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4127133/
https://ncbi.nlm.nih.gov/pubmed/24801708
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201402449
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