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Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes
A highly enantio- and regioselective copper-catalyzed hydroamination reaction of alkenes has been developed using diethoxy(methyl)silane (DEMS) and esters of hydroxylamines. The process tolerates a wide variety of substituted styrenes, including trans-, cis-, and β,β-disubstituted styrenes to yield...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3874865/ https://ncbi.nlm.nih.gov/pubmed/24106781 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4092819 |
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