A carregar...
N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P–P bond and its subsequent reactivity
The room temperature reaction of a 1 : 1 mixture of phosphorus tribromide (PBr(3)) and the N-heterocyclic carbene 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) quantitatively affords the Lewis acid–base adduct (IPr)PBr(3) (1). Interestingly, when 1 is heated between 55 and 65 °C for a peri...
Na minha lista:
| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5356258/ https://ncbi.nlm.nih.gov/pubmed/28451133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02343f |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|