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Actinide tetra-N-heterocyclic carbene ‘sandwiches’

Highly-symmetrical, thorium and uranium octakis-carbene ‘sandwich’ complexes have been prepared by ‘sandwiching’ the An(iv) cations between two anionic macrocyclic tetra-NHC ligands, one with sixteen atoms and the other with eighteen atoms. The complexes were characterized by a range of experimental...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: DeJesus, Joseph F., Kerr, Ryan W. F., Penchoff, Deborah A., Carroll, Xian B., Peterson, Charles C., Arnold, Polly L., Jenkins, David M.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8188502/
https://ncbi.nlm.nih.gov/pubmed/34168841
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01007g
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