Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes

A series of rare earth complexes of the form Ln(L(R))(3) supported by bidentate ortho-aryloxide–NHC ligands are reported (L(R) = 2-O-3,5-(t)Bu(2)-C(6)H(2)(1-C{N(CH)(2)N(R)})); R = (i)Pr, (t)Bu, Mes; Ln = Ce, Sm, Eu). The cerium complexes cleanly and quantitatively insert carbon dioxide exclusively i...

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Publicat a:Chem Sci
Autors principals: Arnold, Polly L., Kerr, Ryan W. F., Weetman, Catherine, Docherty, Scott R., Rieb, Julia, Cruickshank, Faye L., Wang, Kai, Jandl, Christian, McMullon, Max W., Pöthig, Alexander, Kühn, Fritz E., Smith, Andrew D.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2018
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6262539/
https://ncbi.nlm.nih.gov/pubmed/30568765
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03312a
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