Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes

A series of rare earth complexes of the form Ln(L(R))(3) supported by bidentate ortho-aryloxide–NHC ligands are reported (L(R) = 2-O-3,5-(t)Bu(2)-C(6)H(2)(1-C{N(CH)(2)N(R)})); R = (i)Pr, (t)Bu, Mes; Ln = Ce, Sm, Eu). The cerium complexes cleanly and quantitatively insert carbon dioxide exclusively i...

Full description

Saved in:
Bibliographic Details
Published in:Chem Sci
Main Authors: Arnold, Polly L., Kerr, Ryan W. F., Weetman, Catherine, Docherty, Scott R., Rieb, Julia, Cruickshank, Faye L., Wang, Kai, Jandl, Christian, McMullon, Max W., Pöthig, Alexander, Kühn, Fritz E., Smith, Andrew D.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2018
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6262539/
https://ncbi.nlm.nih.gov/pubmed/30568765
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03312a
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items