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Reactivity of Cyclic (Alkyl)(amino)carbenes (CAACs) and Bis(amino)cyclopropenylidenes (BACs) with Heteroallenes: Comparisons with their N-heterocyclic Carbene (NHCs) Counterparts
Similarly to NHCs, CAAC(a) and BAC(a) react with CO(2) to give the corresponding betaines. Based on the carbonyl stretching frequencies of cis-[RhCl(CO)(2)(L)] complexes, the order of electron donor ability was predicted to be CAAC(a) ≈ BAC(a) > NHCs. When the betaines ν(asym)(CO(2)) values are u...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2009
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2869243/ https://ncbi.nlm.nih.gov/pubmed/19780080 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.200900338 |
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