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A Chiral Macrocyclic Tetra-N-heterocyclic Carbene Yields an “All Carbene” Iron Alkylidene Complex
The first chiral macrocyclic tetra-N-heterocyclic carbene (NHC) ligand has been synthesized. The macrocycle, prepared in high yield and large scale, was ligated onto palladium and iron to give divalent C(2)-symmetric square planar complexes. Multinuclear NMR and single crystal X-ray diffraction demo...
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| Yayımlandı: | Chemistry |
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| Asıl Yazarlar: | , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2020
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7024548/ https://ncbi.nlm.nih.gov/pubmed/31788868 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905360 |
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