Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination

Diphosphene Ter(Mes)P = PTer(Mes) (1; Ter(Mes) = 2,6-Mes(2)C(6)H(3); Mes = 2,4,6-Me(3)C(6)H(2)) and NHC(Me(4))2 (NHC(Me(4)) = 1,3,4,5-tetramethylimidazol-2-ylidene) exist in an equilibrium mixture with the NHC(Me(4))-coordinated diphosphene 3. While uncoordinated 1 is inert to hydrolysis, the NHC ad...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Dhara, Debabrata, Kalita, Pankaj, Mondal, Subhadip, Narayanan, Ramakirushnan Suriya, Mote, Kaustubh R., Huch, Volker, Zimmer, Michael, Yildiz, Cem B., Scheschkewitz, David, Chandrasekhar, Vadapalli, Jana, Anukul
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5944230/
https://ncbi.nlm.nih.gov/pubmed/29780553
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00348c
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