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Direct access to 2-aryl substituted pyrrolinium salts for carbon centre based radicals without pyrrolidine-2-ylidene alias cyclic(alkyl)(amino)carbene (CAAC) as a precursor
The synthesis of organic radicals is challenging due to their inherent instability. In recent years, cyclic(alkyl)(amino)carbene (CAAC)-derived 2-substituted pyrrolinium salts have been used as synthons for the synthesis of isolable carbon-based radicals. Herein, we report a direct, easy and conveni...
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Publicado no: | Chem Sci |
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Main Authors: | , , , , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Royal Society of Chemistry
2019
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6470959/ https://ncbi.nlm.nih.gov/pubmed/31049189 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05477k |
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