Direct access to 2-aryl substituted pyrrolinium salts for carbon centre based radicals without pyrrolidine-2-ylidene alias cyclic(alkyl)(amino)carbene (CAAC) as a precursor

The synthesis of organic radicals is challenging due to their inherent instability. In recent years, cyclic(alkyl)(amino)carbene (CAAC)-derived 2-substituted pyrrolinium salts have been used as synthons for the synthesis of isolable carbon-based radicals. Herein, we report a direct, easy and conveni...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Mandal, Debdeep, Sobottka, Sebastian, Dolai, Ramapada, Maiti, Avijit, Dhara, Debabrata, Kalita, Pankaj, Narayanan, Ramakirushnan Suriya, Chandrasekhar, Vadapalli, Sarkar, Biprajit, Jana, Anukul
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2019
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6470959/
https://ncbi.nlm.nih.gov/pubmed/31049189
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05477k
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