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Stable P-Heterocyclic Carbenes: Scope and Limitations

The conjugate acids (PHCH (+)s) of P-heterocyclic carbenes (PHCs) are prepared by formal [3+2] cycloaddition of a 1,3-diphosphaallyl or 1,3-phosphinophosphenium cation with various nitriles. The effect of the phosphorus substituent on the fate of the cyclization and on that of the counteranion and b...

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Auteurs principaux: Masuda, Jason D., Martin, David, Lyon-Saunier, Celine, Baceiredo, Antoine, Gornitzka, Heinz, Donnadieu, Bruno, Bertrand, Guy
Format: Artigo
Langue:Inglês
Publié: 2007
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2427278/
https://ncbi.nlm.nih.gov/pubmed/17441152
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.200600300
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