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Cyclic (Amino)[bis(ylide)]carbene as an Anionic Bidentate Ligand for Transition Metal Complexes
The 3-triphenylphosphonio-N-(2,6-diisopropylphenyl)-pyrole reacts with two equivalents of methyl lithium to afford a lithium adduct in which a cyclic (amino)[bis(ylide)]carbene, a novel type of NHC, acts as a 1,4-bidentate ligand via the carbene center and the exocyclic ylidic carbon. This species r...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2574712/ https://ncbi.nlm.nih.gov/pubmed/18422308 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic800459p |
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