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New Synthetic Routes to C-Amino Phosphorus Ylides and their Subsequent Fragmentation into Carbenes and Phosphines
Phosphonio-substituted aldiminium, iminium and imidazolidinium salts are readily prepared in excellent yields by addition of phosphines to Alder’s dimer, or by treatment of the corresponding chloro iminium salt with the in situ generated phosphine/trimethylsilyl triflate adduct. A two-electron reduc...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2427273/ https://ncbi.nlm.nih.gov/pubmed/17441050 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.200600075 |
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