New Synthetic Routes to C-Amino Phosphorus Ylides and their Subsequent Fragmentation into Carbenes and Phosphines

Phosphonio-substituted aldiminium, iminium and imidazolidinium salts are readily prepared in excellent yields by addition of phosphines to Alder’s dimer, or by treatment of the corresponding chloro iminium salt with the in situ generated phosphine/trimethylsilyl triflate adduct. A two-electron reduc...

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Hlavní autoři: Conejero, Salvador, Song, Maoying, Martin, David, Canac, Yves, Soleilhavoup, Michèle, Bertrand, Guy
Médium: Artigo
Jazyk:Inglês
Vydáno: 2006
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2427273/
https://ncbi.nlm.nih.gov/pubmed/17441050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.200600075
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