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Stable four-π-electron, four-membered heterocyclic cations and carbenes
Replacement of halide from N-(haloboryl)formamidines for the weakly coordinating anion [B(C(6)F(5))(4)](−), using [Et(3)Si(toluene)](+)[B(C(6)F(5))(4)](−), induces a ring closure leading to the cationic four-π-electron four-membered heterocycles [HC(N-2,6-diisopropylphenyl)(2)BR](+) [R = N(i-Pr)(2),...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1564229/ https://ncbi.nlm.nih.gov/pubmed/16950877 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0604761103 |
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