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Mechanism of Nucleophilic Activation of (−)-Lomaiviticin A

(−)-Lomaiviticin A (1) is a C(2)-symmetric cytotoxin that contains two diazofluorene functional groups and which induces double-strand breaks (DSBs) in DNA. Evidence suggests DNA cleavage is initiated by hydrogen atom abstraction from the deoxyribose backbone. Here we demonstrate the formation of th...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Xue, Mengzhao, Herzon, Seth B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5339879/
https://ncbi.nlm.nih.gov/pubmed/27934014
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09657
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