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The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

[Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine...

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Detalles Bibliográficos
Publicado en:J Am Chem Soc
Main Authors: Dauth, Alexander, Gellrich, Urs, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2017
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5330656/
https://ncbi.nlm.nih.gov/pubmed/28141925
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13050
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