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The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

[Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine...

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Опубликовано в: :J Am Chem Soc
Главные авторы: Dauth, Alexander, Gellrich, Urs, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Формат: Artigo
Язык:Inglês
Опубликовано: American Chemical Society 2017
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5330656/
https://ncbi.nlm.nih.gov/pubmed/28141925
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13050
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