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The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

[Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Dauth, Alexander, Gellrich, Urs, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5330656/
https://ncbi.nlm.nih.gov/pubmed/28141925
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b13050
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