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Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium

A sustainable, new synthesis of oxalamides, by acceptorless dehydrogenative coupling of ethylene glycol with amines, generating H(2), homogeneously catalyzed by a ruthenium pincer complex, is presented. The reverse hydrogenation reaction is also accomplished using the same catalyst. A plausible reac...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Zou, You-Quan, Zhou, Quan-Quan, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159388/
https://ncbi.nlm.nih.gov/pubmed/34123004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02065f
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