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Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes

[Image: see text] Base-metal catalyzed dehydrogenative self-coupling of 2-amino alcohols to selectively form functionalized 2,5-substituted pyrazine derivatives is presented. Also, 2-substituted quinoxaline derivatives are synthesized by dehydrogenative coupling of 1,2-diaminobenzene and 1,2-diols....

詳細記述

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書誌詳細
出版年:ACS Catal
主要な著者: Daw, Prosenjit, Kumar, Amit, Espinosa-Jalapa, Noel Angel, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
フォーマット: Artigo
言語:Inglês
出版事項: American Chemical Society 2018
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6503583/
https://ncbi.nlm.nih.gov/pubmed/31080687
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b02208
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