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Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)(2)Si(Me)H as a Stoichiometric Reductant

While attempting to effect Co-catalyzed hydrosilylation of β-vinyl trimethylsilyl enol ethers we discovered that depending on the silane, solvent and the method of generation of the reduced cobalt catalyst, a highly efficient and selective reduction or hydrosilylation of an alkene can be achieved. T...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:ACS Catal
Prif Awduron: Raya, Balaram, Biswas, Souvagya, RajanBabu, T. V.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2016
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5222586/
https://ncbi.nlm.nih.gov/pubmed/28078166
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b02272
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