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Control of Selectivity through Synergy between Catalysts, Silanes and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes
Readily accessible ((i)(-Pr)PDI)CoCl(2) [(i)(-Pr) PDI = 2,6-bis(2,6-diisopropylphenyliminoethyl)pyridine] reacts with 2 equivalents of NaEt(3)BH at −78 °C in toluene to generate a catalyst that effects highly selective anti-Markovnikov hydrosilylation of the terminal double bond in 1,3- and 1,4-dien...
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| Publicado no: | ACS Catal |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5459319/ https://ncbi.nlm.nih.gov/pubmed/28593082 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b03373 |
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