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Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)(2)Si(Me)H as a Stoichiometric Reductant
While attempting to effect Co-catalyzed hydrosilylation of β-vinyl trimethylsilyl enol ethers we discovered that depending on the silane, solvent and the method of generation of the reduced cobalt catalyst, a highly efficient and selective reduction or hydrosilylation of an alkene can be achieved. T...
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| 出版年: | ACS Catal |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5222586/ https://ncbi.nlm.nih.gov/pubmed/28078166 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b02272 |
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