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Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes
Mono- and 2,2′-di-substituted terminal alkenes can be isomerized into the more stable internal Z- and E- alkenes by treating them with catalytic amounts of [(allyl)PdCl](2) or [(allyl)NiBr](2), a triarylphosphine and silver triflate at room temperature. The isomeric ratio (E:Z) depends on the alkene...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2009
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2715430/ https://ncbi.nlm.nih.gov/pubmed/19441793 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo900180p |
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