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Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs
We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be a...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6446965/ https://ncbi.nlm.nih.gov/pubmed/30996968 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00126c |
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