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Magnesium hydride alkene insertion and catalytic hydrosilylation
The dimeric β-diketiminato magnesium hydride, [(BDI)MgH](2), reacts at 80 °C with the terminal alkenes, 1-hexene, 1-octene, 3-phenyl-1-propene and 3,3-dimethyl-butene to provide the respective n-hexyl, n-octyl, 3-phenylpropyl and 3,3-dimethyl-butyl magnesium organometallics. The facility for and the...
Tallennettuna:
| Julkaisussa: | Chem Sci |
|---|---|
| Päätekijät: | , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
Royal Society of Chemistry
2019
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6839609/ https://ncbi.nlm.nih.gov/pubmed/31814958 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02056j |
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