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A Theoretical Investigation of the Ni(II)-Catalyzed Hydrovinylation of Styrene

We report a detailed and full computational investigation on the hydrovinylation reaction of styrene with the Ni(II)-phospholane catalytic system, which was originally presumed to proceed through a cationic mechanism involving a nickel hydride intermediate. The following general features emerge from...

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Autori principali: Joseph, Jorly, RajanBabu, T. V., Jemmis, Eluvathingal D.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2009
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3083920/
https://ncbi.nlm.nih.gov/pubmed/21532981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om900045p
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