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Diels-Alder Reactions of Furans with Itaconic Anhydride: Overcoming Unfavorable Thermodynamics

Unfavorable thermodynamics often render furans reluctant to engage in high-yielding Diels-Alder (DA) cycloaddition reactions. Here we report the highly efficient conversion of the bio-sourced reactants itaconic anhydride (IA) and furfuryl alcohol (FA) to a single DA adduct. The free energy advantage...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Org Lett
Egile Nagusiak: Pehere, Ashok D., Xu, Shu, Thompson, Severin K., Hillmyer, Marc A., Hoye, Thomas R.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2016
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5136459/
https://ncbi.nlm.nih.gov/pubmed/27214494
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00929
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