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Diels-Alder Reactions of Furans with Itaconic Anhydride: Overcoming Unfavorable Thermodynamics
Unfavorable thermodynamics often render furans reluctant to engage in high-yielding Diels-Alder (DA) cycloaddition reactions. Here we report the highly efficient conversion of the bio-sourced reactants itaconic anhydride (IA) and furfuryl alcohol (FA) to a single DA adduct. The free energy advantage...
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| 出版年: | Org Lett |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5136459/ https://ncbi.nlm.nih.gov/pubmed/27214494 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00929 |
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