Reactivity of an Fe(IV)–Oxo Complex with Protons and Oxidants

High valent Fe–OH species are often invoked as key intermediates but have only been observed in Compound II of cytochrome P450s. To further address the properties of non-heme Fe(IV)–OH complexes we demonstrate the reversible protonation of a synthetic Fe(IV)–oxo species containing a tris-urea tripod...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Hill, Ethan A., Weitz, Andrew C., Onderko, Elizabeth, Romero-Rivera, Adrian, Guo, Yisong, Swart, Marcel, Bominaar, Emile L., Green, Michael T., Hendrich, Michael P., Lacy, David C., Borovik, A. S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5110122/
https://ncbi.nlm.nih.gov/pubmed/27647293
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b07633
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