Reactivity of an Fe(IV)–Oxo Complex with Protons and Oxidants

High valent Fe–OH species are often invoked as key intermediates but have only been observed in Compound II of cytochrome P450s. To further address the properties of non-heme Fe(IV)–OH complexes we demonstrate the reversible protonation of a synthetic Fe(IV)–oxo species containing a tris-urea tripod...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Hill, Ethan A., Weitz, Andrew C., Onderko, Elizabeth, Romero-Rivera, Adrian, Guo, Yisong, Swart, Marcel, Bominaar, Emile L., Green, Michael T., Hendrich, Michael P., Lacy, David C., Borovik, A. S.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2016
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Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5110122/
https://ncbi.nlm.nih.gov/pubmed/27647293
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b07633
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