Effects of Non-covalent Interactions on High-spin Fe(IV)–oxido Complexes

High-valent non-heme Fe(IV)–oxido species are key intermediates in biological oxidation, and their properties are proposed to be influenced by the unique microenvironments present in protein active sites. Microenvironments are regulated by non-covalent interactions, such as hydrogen bonds (H-bonds)...

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Publicado en:J Am Chem Soc
Autores principales: Oswald, Victoria F., Lee, Justin L., Biswas, Saborni, Weitz, Andrew C., Mittra, Kaustuv, Fan, Ruixi, Li, Jikun, Zhao, Jiyong, Hu, Michael Y., Alp, Esen E., Bominaar, Emile L., Guo, Yisong, Green, Michael T., Hendrich, Michael P., Borovik, A.S.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2020
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7899053/
https://ncbi.nlm.nih.gov/pubmed/32489096
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03085
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