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Conformational Control of Chiral Amido-Thiourea Catalysts Enables Improved Activity and Enantioselectivity
While aryl pyrrolidinoamido thioureas derived from α-amino acids are effective catalysts in a number of asymmetric transformations, they exist as mixtures of slowly interconverting amide rotamers. Herein, the compromising role of amide bond isomerism is analyzed experimentally and computationally. A...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5096793/ https://ncbi.nlm.nih.gov/pubmed/27294369 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01435 |
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