Lanean...
Conformational Control of Chiral Amido-Thiourea Catalysts Enables Improved Activity and Enantioselectivity
While aryl pyrrolidinoamido thioureas derived from α-amino acids are effective catalysts in a number of asymmetric transformations, they exist as mixtures of slowly interconverting amide rotamers. Herein, the compromising role of amide bond isomerism is analyzed experimentally and computationally. A...
Gorde:
| Argitaratua izan da: | Org Lett |
|---|---|
| Egile Nagusiak: | , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2016
|
| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5096793/ https://ncbi.nlm.nih.gov/pubmed/27294369 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01435 |
| Etiketak: |
Etiketa erantsi
Etiketarik gabe, Izan zaitez lehena erregistro honi etiketa jartzen!
|