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Mechanism-Guided Development of a Highly Active Bis-Thiourea Catalyst for Anion-Abstraction Catalysis
We describe the rational design of a linked, bis-thiourea catalyst with enhanced activity relative to monomeric analogs in a representative enantioselective anion-abstraction reaction. Mechanistic insights guide development of this linking strategy to favor substrate activation though the intramolec...
Shranjeno v:
| izdano v: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5380606/ https://ncbi.nlm.nih.gov/pubmed/27704810 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09205 |
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