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On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis
Chiral, neutral H-bond donors have found widespread use as catalysts in enantioselective reactions involving ion-pair intermediates. Herein, a systematic mechanistic study of a prototypical anion-binding reaction, the thiourea-catalyzed enantioselective alkylation of α-chloroethers, is detailed. Thi...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5108296/ https://ncbi.nlm.nih.gov/pubmed/27276389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04686 |
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