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Thiourea-Catalyzed Enantioselective Cyanosilylation of Ketones
[Image: see text] The new chiral amino thiourea catalyst 3d promotes the highly enantioselective cyanosilylation of a wide variety of ketones. The hindered tertiary amine substituent plays a crucial role both with regard to stereoinduction and reactivity, suggesting a cooperative mechanism involving...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2005
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3166885/ https://ncbi.nlm.nih.gov/pubmed/15969569 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja052511x |
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