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Enantioselective Thiourea-Catalyzed Intramolecular Cope-Type Hydroamination
Catalysis of Cope-type rearrangements of bishomoallylic hydroxylamines is demonstrated using chiral thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched α-substituted pyrrolidine products, and represents a complementary approach to metal-...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3689223/ https://ncbi.nlm.nih.gov/pubmed/23597402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402893z |
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