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Highly Enantioselective Iridium‐Catalyzed Hydrogenation of Cyclic Enamides
The MaxPHOX–Ir catalyst system provided the highest selectivity ever reported for the reduction of cyclic enamides derived from α‐ and β‐tetralones. This result indicates that iridium catalysts are also proficient in reducing alkenes bearing metal‐coordinating groups. In the present system, selectiv...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2016
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5084810/ https://ncbi.nlm.nih.gov/pubmed/27186653 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201602219 |
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